I created a table that is embedded in a beamer presentation:
\documentclass[10pt, aspectratio=169]{beamer}
\usefonttheme{serif}
\usepackage{booktabs} % tables
\usepackage{amsmath} % align,
\usepackage{siunitx} % units, numbers
\usepackage{mathtools}
\usepackage[singlelinecheck=false]{caption}
\usepackage{tabularray}
\UseTblrLibrary{amsmath,booktabs}
\setbeamerfont{caption}{size=\footnotesize}
\setbeamertemplate{caption label separator}[space]
\begin{document}
\begin{frame}{}
\scriptsize
\begin{table}
\captionsetup{font=scriptsize}
\qquad
\begin{minipage}{0.342\linewidth}
\caption{Title}
\vspace{-1ex}
\begin{tblr}{hline{1,Z},colspec={@{} l Q[l, mode={math}] @{}},rowsep=1pt}
A&L\textsubscript{a}=\qty{11}{km}\\
B&L\textsubscript{b}=\qty{1000}{km}\\
C&L\textsubscript{c}=\qty{150}{km}\\
\end{tblr}
\end{minipage}
\end{table}
\end{frame}
\end{document}
- How can I add additional columns? (should be 3 rows x 7 columns)
- How can I add the column names?

tabularry? You specify two columns currently, one is text mode, one is math mode. You should describe more specific what kind of additional columns you'd like to add. And why did you tag this question withmulticolumn?