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Structures of 135 organic compounds and transition metal complexes with experimental molecular static polarizabilities.

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Benchmark set for static molecular polarizabilities

The data of this repository has been extracted from the supporting information of Ref. (Thakkar, 2015). All structures have been optimized using density functional theory at the CAM-B3LYP-D3(BJ)/def2-TZVP level of theory.

Reference values

All experimental reference values are given in Bohr3 the file references.data. The first letter in parentheses denotes the type of experiment:

  • O : dipole oscillator
  • R : refractive index
  • D : dielectric permittivity
  • A : combined R and D data
  • E : electron-molecule scattering

An H after the comma denoted the high temperature experiment.

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Structures of 135 organic compounds and transition metal complexes with experimental molecular static polarizabilities.

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